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Preparation of carrageenan/chitosan-based N, N, N-trimeth yl chitosan chloride silver nanocomposites as pH sensitive carrier for effective controlled curcumin delivery in cancer cells

It releases constituent metal ions into the aqueous phase, creating a mixed exposure scenario.85 The dissolution rate (dC/dt) is governed by the NoyesWhitney framework but is critically modulated by environmental factors.86 Kinetic data show that dissolution half-lives (t1/2) vary by orders of magnitude: ZnO nanoparticles may exhibit a t1/2 of mere hours in acidic waters (pH 5) versus weeks in neutral, NOM-rich waters where surface passivation occurs.87,88 This pathway is the mechanistic basis of the Trojan Horse hypothesis.7173,75 Surface transformations and the eco-corona: defining the bio-nano interface The surface of an ENM is its active interface with the environment

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TABLE 1 The scoring criteria of DAI