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Biochem Pharmacol 46:257263 Jaeschke H, Wendel A (1985) Diurnal fluctuation and pharmacological alteration of mouse organ glutathione content

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vii) first- and second-order asymmetric transformationsa technique whereby diastereomers from the racemate equilibrate to yield a preponderance in solution of the diastereomer from the desired enantiomer or where preferential crystallization of the diastereomer from the desired enantiomer perturbs the equilibrium such that eventually in principle all the material is converted to the crystalline diastereomer from the desired enantiomer