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Here we report an artificial glyoxalase I, which successfully catalyses the enantioselective isomerization of hemithioacetal adducts, spontaneously formed between a range of toxic 2-oxoaldehydes and thiols as GSH surrogates, into high-valued chiral -hydroxy thioesters with excellent yields and enantioselectivities

University of Tennessee Medical Center

Theoretically, such effects could be involved in reductive or oxidative signaling through increases or decreases, respectively, in NADPH-NADP+ ratios

Meanwhile, those at risk for certain cancers are more interested in lowering their levels (5, 7, 8)